A Product Carbon Footprint (PCF) measures the greenhouse gas (GHG) emissions across the life cycle of a product. This involves going step-by-step along all processes involved in the production of the product, and measuring all the emissions that occur at each process (including emissions from the onsite use and offsite production of fuels, electricity and materials).
This calculation is straightforward when each process only creates one single output product. But sometimes a single process can create more than one product. This could include:
A valuable product(s) and a waste product(s)
A valuable product(s) and a low-value by-product(s)
Multiple valuable products
In these cases, the emissions that arise from the process need to be allocated between the different outputs.
But how should the emissions be allocated? Should each product be assigned an equal proportion of emissions? Should the emissions be allocated based on certain inherent characteristics of the products (their mass or their volume)? Should the allocation be based on the relative value of each product?
Welcome to the world of allocation in carbon accounting.
The Greenhouse Gas Protocol Product Standard sets out the requirements and guidelines for businesses to follow when making decisions about how to allocate emissions between products.
"Companies shall allocate emissions and removals to accurately reflect the contributions of the studied product and co-product(s) to the total emissions and removals of the common process."
(Greenhouse Gas Protocol Product Standard)
In other words: don't assign any emissions to waste products. Non-waste products get allocated 100% of the emissions.
"Companies shall avoid allocation wherever possible by using process subdivision, redefining the functional unit, or using system expansion."
(Greenhouse Gas Protocol Product Standard)
In other words: can you undertake one of the following options instead?
Can you divide your process into sub-processes, so that each sub-process produces only one product?
For example:
Can you redefine your product under analysis to include the co-product?
Examples:
Sometimes, your production of the co-product means that you have avoided the need for that co-product to be produced by another facility elsewhere.
System expansion gives an 'emissions credit' for this avoided production.
For example:
In summary, if you can avoid allocation by subdividing your process, changing the definition of your product, or subtracting emissions from avoided production, you should.
"If allocation is unavoidable, companies shall allocate emissions and removals based on the underlying physical relationships between the studied product and co-product(s). When physical relationships alone cannot be established or used as the basis for allocation, companies shall select either economic allocation or another allocation method that reflects other relationships between the studied product and co-product."
(Greenhouse Gas Protocol Product Standard)
If it is not possible to avoid allocation, you should first allocate based on the inherent physical characteristics of the product (i.e. mass, volume).
Where this doesn't make sense, then you should undertake economic allocation (or another allocation method), explained below.
Besides the Greenhouse Gas Protocol, other common 'rule books' for product carbon footprinting include:
The ISO 14040/44 and EN 15804 standards follow the same allocation rules as the Greenhouse Gas Protocol Product Standard. The ISO 14067 standard, however, does not allow the use of system expansion as a method for avoiding allocation.
Physical allocation is where you allocate emissions based on a physical relationship between the co-products. The most common example is mass allocation, although volume, metal content or other physical relationships are also possible.
In mass allocation, the relative mass of each product determines the proportion of total emissions assigned to each product.
For example:
A gold mine produced 15 tonnes of gold and 50,000 tonnes of copper, and calculates its emissions at 300,000 tCO2e in 2023.
Using mass allocation:
On a per tonne basis, the gold and the copper would each have an emissions intensity of 6.0 tCO2e/t.
Note: The data used in this example is not based on any study, and is for illustrative purposes only.
Economic allocation, as the name implies, involves the allocation of emissions based on the economic value of the co-products. The relative value of each product determines the proportion of total emissions assigned to each product.
For example:
Gold is worth $65,000,000 per tonne. Copper is worth $5,000 per tonne. A gold mine produced 15 tonnes of gold and 50,000 tonnes of copper, and calculates its emissions at 300,000 tCO2e in 2023.
Using economic allocation:
On a per tonne basis:
If allocation can't be avoided, then when co-products have widely disparate economic values, economic allocation is usually the best allocation option. This is because it represents the best allocation of why emissions occur.
Our gold-copper mine example is useful in illustrating this point. To recap the example:
In this example, gold represents 0.03% of the mass, but 80% of the revenue of the mine. If the mine no longer produced copper, the mine would lose 20% of its revenue, but may decide to continue operating (and continue emitting 300,000 tCO2e every year).
However, if the mine were to stop producing gold, it would lose 80% of its revenue, and would probably decide to close (and therefore the 300,000 tCO2e would no longer be emitted).
Therefore, economic allocation is the best approximator of assigning emissions between the two co-products.
As you can see, different allocation methods are appropriate in different situations. In instances where allocation is necessary in product carbon footprintig, CarbonChain follows the following decision-making hierarchy:
Metal producers, processors, distributors and traders use CarbonChan for accurate carbon accounting across all key reporting needs — so they can satisfy regulatory and stakeholder demands and gain a competitive edge.
CarbonChain uses economic allocation according to the following best practice:
Using economic allocation means that as relative prices change over time, the emissions assigned to each of the co-products will change too, even when the total emissions of the underlying process remain constant.
In the world of metal commodities, prices can change significantly year-on-year (and even day-on-day).
In order to counteract this, CarbonChain's platform uses average prices over a ten-year period in its economic allocation calculations for metals. However, the total emissions from the process, and the total production volumes of the process, are still calculated using annual data.
CarbonChain uses economic allocation for all metal production routes that produce multiple metallic products, where the metals are distinct.
For example:
When two products contain the same metal, economic allocation is not required; for example, a site may produce both nickel sulphate and mixed sulphide precipitate (which is a nickel-containing product). In this case, CarbonChain would allocate based on the relative nickel contents of the two products.
The GHG protocol product standard and the ISO standards (14040, 14044, 14067, EN 15804) provide general guidance on allocation. Different metal associations and other organisations have produced specific guidance on the use of allocation for specific metals:
International Aluminum's Aluminum Carbon Footprint Methodology
Cobalt Institute's Determining the Global Warming Potential of Cobalt.
International Copper Association's Carbon Footprint of Copper Production.
Nickel Institute's How to determine GHG emissions from nickel metal Class 1 production.
International Platinum Group Metals Association's The Carbon Footprint of Platinum Group Metals.
International Zinc Association's Technical Guidance on Carbon Footprint Calculation for Special High-Grade Zinc.